Improving electrochemical performance of NMC811 battery cathode with Indonesian rice husk-derived silica surface coating

Penulis: Angellinnov, FionaSubhan, AchmadIvandini, Tribidasari A.Sumboja, AfriyantiPriyono, Bambang
Informasi
Jurnale-Prime - Advances in Electrical Engineering, Electronics and Energy
PenerbitElsevier Ltd
Volume & EdisiVol. 13
Halaman -
Tahun Publikasi2025
ISSN27726711
Jenis SumberScopus
Sitasi
Scopus: 1
Google Scholar: 1
PubMed: 1
Abstrak
Nickel-rich nickel manganese cobalt (LiNixMnyCozO2 x ≥ 0.8) cathode material is widely studied due to its high specific capacity, high energy density, and low toxicity. Despite these advantages, NMC811 (LiNi0.8Mn0.1Co0.1O2) suffers from structural instability and is susceptible to degradation upon exposure to ambient air. Surface coating using silica has been demonstrated to mitigate these issues by acting as a protective barrier against air and electrolyte. In the present study, rice husk was used as a cost-effective and renewable source of silica for coating NMC811. The extracted silica was characterized by an amorphous structure, spherical particles, and a purity of 97.54%. Coating with 1.5 wt.% rice husk-derived silica improved electrochemical performance of NMC811, yielding enhancements in electrical conductivity (3.11 × 10-5 S/cm), lithium-ion diffusion coefficient (9.77 × 10-14 cm2/s), and specific capacity (325.30 mAh/g) in comparison to pristine NMC811 (2.68 × 10-5 S/cm, 3.63 × 10-14 cm2/s, 212.93 mAh/g, respectively). These findings highlight the potential of rice husk-derived silica as sustainable and effective coating material for enhancing the stability and electrochemical performance of NMC811 cathodes. © 2025 The Authors
Dokumen & Tautan

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