In this work, LaFeO3 was synthesized via the sol–gel method and characterized to evaluate its potential for ultrafast humidity sensing applications. X-ray diffraction (XRD) confirmed the formation of a single-phase orthorhombic structure with a Pnma space group and high crystallinity. Scanning electron microscopy (FE-SEM) revealed a relatively homogeneous porous grain structure, while energy-dispersive X-ray spectroscopy (EDX) verified the presence of La, Fe, and O with stoichiometric weight percentages of 50.0%, 29.8%, and 20.2%, respectively. The sensing layer was deposited onto an interdigital transducer (IDT) with an Al2O3 (alumina) substrate, and capacitance measurements using an LCR meter at 100Hz were performed in the 11–96% relative humidity (RH) range at room temperature. The sensor exhibited a capacitance increase from 26.93pF (11% RH) to 603.73pF (96% RH), with an average hysteresis value of 6.2%, response and recovery times of 9.7s and 1.2s, respectively, and a maximum sensitivity of 6.78pF/%RH at 96% RH. These results indicate that LaFeO3 is a promising candidate for the development of efficient, stable, and fast-response humidity sensors for practical applications in environmental monitoring and industrial process control. © 2026 The Author(s)